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De-icing is the process of removing ice from a surface. Anti-icing is the process of preventing ice from forming on a surface. Freezing-point depression describes the phenomenon that the freezing point of a liquid (a solvent) is depressed when another compound is added, meaning that a solution has a lower freezing point than a pure solvent. This happens whenever a solute is added to a pure solvent, such as water. The phenomenon may be observed in sea water, which due to its salt content remains liquid at temperatures below 0°C, the freezing point of pure water. De-icing can be accomplished by mechanical methods (scraping), through the application of heat, by use of chemicals designed to lower the freezing point of water (various salts or alcohols), or a combination of these different techniques. Roads De-icing of roads has traditionally been done with salt, spread by snowplows or other dump trucks designed to spread it, along with sand and gravel, on slick roads. Sodium chloride (rock salt) is normally used, as it is inexpensive and readily available in large quantities. However, since salt water still freezes at -18°C or 0°F, it is of no help when the temperature falls below this point. It also has a strong tendency to cause corrosion, rusting the steel used in most vehicles and the rebar used in concrete bridges. More recent snowmelters use other salts, such as calcium chloride and magnesium chloride, which not only depress the freezing point of water to a much lower temperature, but also produce an exothermic reaction. They are somewhat safer for concrete sidewalks, but excess should still be removed. More recently, organic compounds have been developed that reduce the environmental issues connected with salts and have longer residual effects when spread on roadways, usually in conjunction with salt brines or solids. These compounds are generated as byproducts of agricultural operations such as sugar beet refining or the distillation process that produces ethanol.[3] Since the 1990s, use of liquid chemical melters has been increasing, being sprayed on roads by nozzles instead of a spinning spreader. Liquid melters are more effective at preventing the ice from bonding to the surface than melting through existing ice. In Nagano, Japan, relatively inexpensive hot water bubbles up through holes in the pavement to melt snow, though this solution is only practical within a city or town. Some individual buildings may melt snow and ice with electric heating elements buried in the pavement, or even on a roof to prevent ice dams under the shingles, or to keep massive chunks of snow and dangerous icicles from collapsing on anyone below. Small areas of pavement can be kept ice-free by circulating heated liquids in embedded piping systems. The phenomenon of freezing point depression is used in technical applications to avoid freezing. In the case of water, ethylene glycol or other forms of antifreeze is added to cooling water in internal combustion engines, making the water stay a liquid at temperatures below its normal freezing point. FDP The use of freezing-point depression through "freeze avoidance" has also evolved in some animals that live in very cold environments. This happens through permanently high concentration of physiologically rather inert substances such as sorbitol or glycerol to increase the molality of fluids in cells and tissues, and thus decrease the freezing point. Examples include some species of arctic-living fish, such as rainbow smelt, which need to be able to survive in freezing temperatures for a long time. In other animals, such as the peeper frog (Pseudacris crucifer), the molality is increased temporarily as a reaction to cold temperatures. In the case of the peeper frog, this happens by massive breakdown of glycogen in the frog's liver and subsequent release of massive amounts of glucose.[4] Together with formula above, freezing-point depression can be used to measure the degree of dissociation or the molar mass of the solute. This kind of measurement is called cryoscopy (Greek "chillawatchsts") and relies on exact measurement of the freezing point. The degree of dissociation is measured by determining the van 't Hoff factor i by first determining mB and then comparing it to msolute. In this case, the molar mass of the solute must be known. The molar mass of a solute is determined by comparing mB with the amount of solute dissolved. In this case, i must be known, and the procedure is primarily useful for organic compounds using a nonpolar solvent. Cryoscopy is no longer as common a measurement method as it once was. As an example, it was still taught as a useful analytic procedure in Cohen's Practical Organic Chemistry of 1910,[5] in which the molar mass of napthalene is determined in a so-called Beckmann freezing apparatus. In principle, the boiling point elevation and the freezing point depression could be used interchangeably for this purpose. However, the cryoscopic constant is larger than the ebullioscopic constant and the freezing point is often easier to measure with precision, which means measurements using the freezing point depression are more precise. |