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Ron的解释:
i think the real problem with the construction in choice (a) is that the clause following "when" is "it is known". in other words, that choice suggests that the fact is (was?) known at that date, an interpretation that clearly doesn't make sense in context.人类用石头做工具是在150,000年前的时候知道的。。。逻辑意思不对
in the correct answer, the "at which" is followed by a clause whose subject is "humans", and which describes the actual action that took place at that date. therefore, i think the idea is that this clause more accurately describes the chronology of the events: i.e., the toolmaking happened at that date, and the fact is known now.
as for your other question, this isn't really a perfect tense, because it's actually not a tense at all -- it's an infinitive.
probably the easiest way to go here is to remember this as an idiomatic usage of the construction "known to". if the action is in the present, then you use "known to VERB"; if the action is in the past, then you use "known to have VERBed". as far as i know, these are the only two possible forms.
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